Subscribe now

Chemistry

Quantum experiment rewrites a century-old chemistry law

The Arrhenius equation, which has accurately described rates of chemical reactions for more than a century, may have to be tweaked for the quantum realm

By Karmela Padavic-Callaghan

9 September 2024

A double potential energy well with quantum wave functions on a ladder of different energy levels

N. E. Frattini et al.

A 135-year-old chemistry law is getting a quantum makeover. An experiment with a single quantum bit, or a qubit, has uncovered that the Arrhenius equation, which describes how reaction rates relate to temperature, must be modified to apply in the quantum realm.

Rodrigo Cortiñas at Yale University says he never doubted that the Arrhenius equation would translate directly to a quantum experiment – until he and…

Article amended on 23 September 2024

We clarified how the Arrhenius equation applies to quantum tunneling

Sign up to our weekly newsletter

Receive a weekly dose of discovery in your inbox! We'll also keep you up to date with New Scientist events and special offers.

Sign up

To continue reading, subscribe today with our introductory offers

Unlock this article

No commitment, cancel anytime*

Offer ends 15 January 2025.

*Cancel anytime within 14 days of payment to receive a refund on unserved issues.

Inclusive of applicable taxes (VAT)

or

Existing subscribers

Sign in to your account